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Because of High Geomagnetic flux. Volcanoes are born from deep Earth activity, they bring up materials from the mantle which are rich in Iron (and other minerals). So when you ground barefoot on volcanic soil/rock, you’re absorbing both electrons & magnetic information, more than you would from plain old sandy or clay soil. Also, the soil near volcanoes is High in charge density That means better electron flow into the body (boosting redox potential), Mitochondrial efficiency, structured water formation inside cells. It’s just the best of all worlds.